Biodegradable Green Composites: Effects of Potassium Permanganate (KMnO4) Treatment on Thermal, Mechanical, and Morphological Behavior of Butea Parviflora (BP) Fibers

This study emphasizes the importance of utilizing biodegradable material Butea parviflora (BP) fiber for sustainable solutions. BP fiber offers numerous ecological benefits, such as being lightweight, biodegradable, and affordable to recycle. The study examines the effects of potassium permanganate (KMnO4) treatment on BP fiber and analyzes its physical and chemical behavior using various methods, including X-ray Diffraction (XRD) analysis, tensile testing, thermogravimetric analysis, thermal conductivity, Scanning Electron Microscopy (SEM), and Fourier Transform Infrared spectroscopic (FTIR) analysis. The results demonstrate that BP fiber possesses low density (1.40 g/cc) and high cellulose content (59.4%), which fosters compatibility between the matrix and resin. XRD analysis indicates a high crystallinity index (83.47%) and crystallite size (6.4 nm), showcasing exceptional crystalline behavior. Treated fibers exhibit improved tensile strength (198 MPa) and Young’s modulus (4.40 GPa) compared to untreated fibers (tensile strength—92 MPa, tensile modulus—2.16 GPa). The Tg-DTA thermograms reveal the fiber’s thermal resistance up to 240 °C with a kinetic activation energy between 62.80–63.46 KJ/mol. Additionally, the lowered thermal conductivity (K) from Lee’s disc experiment suggests that BP fiber could be used in insulation applications. SEM photographic results display effective surface roughness for composite making, and FTIR studies reveal vibrational variations of cellulosic functional groups, which correlates with increased cellulosic behavior. Overall, the study affirms the potential of BP fiber as a reinforcing material for composite-making while emphasizing the importance of utilizing biodegradable materials for sustainability.


Introduction
Technological advancement provides valuable resources along with ruins that are primarily non-biodegradable. There are high hopes that bio composites infused with natural fibers will attain a pollution-free environment and reduce synthetic acquisition. Reduced mass fraction and density are the two key variables that prioritize the use of natural fibers as reinforcements. A key factor that impacts the utility and availability of product in the market is its structural design, which is predominantly overtaken by synthetic materials. Now, the natural fiber composites are turning out to be trend-setters with their adaptability while retarding moisture absorption [17]. Characterization tests such as X-ray diffraction, physiochemical analysis, mechanical testing, thermogravimetric and thermal conductivity studies, SEM examination, and FTIR functional group analysis gave a wide affirmation for accepting BP fiber as reinforcement for composite applications.
The innovation of this study lies in the utilization of Butea parviflora (BP) fiber as a sustainable and biodegradable material for composite making. The study showcases the exceptional properties of BP fiber, including its high cellulose content, low density, and high crystallinity index, which make it a suitable reinforcing material for composites. Additionally, the study examines the effects of potassium permanganate treatment on BP fiber, which enhances its tensile strength and Young's modulus, improves its thermal stability, and lowers its thermal conductivity, making it suitable for insulation applications. The findings of this study open up new avenues for utilizing BP fiber as a sustainable and environmentally friendly material in the composite industry. Moreover, the study highlights the importance of utilizing biodegradable materials for sustainability, which is essential for promoting a greener and cleaner environment. Overall, the innovation of this study lies in the potential of BP fiber as a sustainable and eco-friendly alternative to conventional reinforcing materials, which could help in reducing the carbon footprint of the composite industry.

Fiber Extraction and Treatment
Butea parviflora (BP) is a woody climber belonging to the Fabaceae family. It is found in the regions of Kanniyakumari, Tamil Nadu. The whole plant is fibrous, but the strength and texture vary from the outer to inner space. Due to its strength, bark fibers of Butea plant are used by locals for tying, knotting, and binding requirements. Bark contains 1% rotenone, which is used as an insecticide. In order to separate mature fibers from the plant, a metal teeth tool is used. Collected fibers are treated in distilled water and potassium permanganate; treatment involves soaking of fibers in 0.1 M NaOH solution for 20 min, followed by 15 min in the same molarity of potassium permanganate at 27 • C. Treated fibers are rinsed in distilled water. Fibers are first drained in shade, then dried completely using a vacuum desiccator. Variation in soaking time and concentration of KMnO 4 will bring varying results. Different treatments at 0.025% and 0.05% of KMnO 4 on the Musa plant eliminated the non-cellulosic debris and manifested the crystalline and tensile property of fiber. The delignification process that takes place during permanganate action facilitates the rearrangement of microfibrils, resulting in an improvement in crystallinity. Moreover, the wetting of fibers in 0.1% KMnO 4 induces capillary forces that increase their resistance to water [18].

Physical Properties
The purpose of chemical procedures is to strengthen the docking of fibers in the composite [7], which has a direct influence on the physical properties as well. Moisture enters through the amorphous region and gets arrested within the microfibrils. NaOH and KMnO4 treatment on fibers will prevent the intrusion of moisture into the core of the com-

Physical Properties
The purpose of chemical procedures is to strengthen the docking of fibers in the composite [7], which has a direct influence on the physical properties as well. Moisture enters through the amorphous region and gets arrested within the microfibrils. NaOH and KMnO 4 treatment on fibers will prevent the intrusion of moisture into the core of the composites; thus, they can endure load and delay the origin of fracture [11,13]. An average of 30 fiber strands are examined and their average values are taken for finding their physical properties. Physical outcomes of Butea fibers are compared with other fibers in Table 1.

Diameter and Aspect Ratios of BP
Diameter and length of BP is observed through an optical microscope and ruler. Modulus of fibers increases with decrease in diameter. Additionally, the fiber's diameter varies with different plant layers. Permanganate treatment on BP fibers reduced the diameter, which would favor a compactivity with the matrix for composite making [19].
High fiber aspect ratios could accelerate the strength of composites [20]. Aspect ratios of permanganate-treated fiber (305) is greater than untreated BP (175). All readings were computed under normal room temperature and pressure.

Linear Density of BP
The fiber's fineness is expressed as mass per unit length since diameter and crosssectional shape are not even along the length. Tensile properties of fiber increases with linear density. Yarned ramie fiber showed improved tensile value, while the linear density was 65 tex [21][22][23]. Linear density is found using, Linear density (LD) = mass of fibers (grams) length of fibers (meter) LD of Butea fibers is higher than Coccinia grandis. Aspect ratio has a direct influence on the better mechanical behavior of the physical traits of fiber. Failure of composites happens at a slower rate when the reinforced fiber has brilliant length-to-diameter ratios [20]. Approximate length taken for analysis is 10 cm.

Density of BP Using Pycnometer
Commercialization of natural fiber-based products over synthetic ones is primarily based on lowered density. Density of carbon (1.8 g/cc) and aramid fibers (1.45 g/cc) are higher than many plant fibers [24]. Alkaline treatment increases the density of fibers by removing less dense non-cellulosic components such as hemicelluloses and lignin [25]. Chemical modification brings a change by lowering the crystal defect and distortion that result in bulk density of fibers [26]. Increased density values in the permanganate-treated Butea fiber satisfy the above reasons. Using the liquid pycnometer method, density was found by inserting toluene as the immersion liquid [27][28][29]. Density is derived from, where m a -empty pycnometer mass; m b -mass of (pycnometer + chopped fibers); m c -mass of (toluene + pycnometer); m d -mass of (toluene + pycnometer + chopped fibers).

XRD Studies
X-ray diffraction is an effective way of exposing the arrangement of atoms, although the main compartments of plants are cellulose and hemicellulose. The analysis was carried out using the Bruker AXS-D8 Advance Model diffractometer, running at 40 kV voltage; 2θ values were taken between 0 • and 70 • . Crystallinity index of BP fiber was analyzed from Segal empirical formula [33] CI BP = I cry-I am I cry × 100% where I cry -intensity at (002) plane, I am -intensity at (110) plane. Using Scherrer's equation, crystallite size is computed [34,35] CS = Kλ β 200 cosθ (4) where K-Scherrer's constant, λ-0.154 nm, β 200 -full width half maximum around 23 • , θ-Bragg's angle.

Single Fiber Tensile Test
Strength of BP along with elongation data from the (Zwick/Roell) instrument are used to determine the tensile modulus of KMnO 4 -treated BP fibers. A relative humidity and temperature of 65% and 21 • C was maintained throughout the experiments. The testing procedure fixed the gauge length to be 50 mm to obtain a transverse rate of 30 mm/min. The microfibrillar angle (α), which plays a vital part in the mechanical output, is obtained from the global deformation equation [30].

Thermogravimetric Studies
Enhanced thermal characteristics of natural fibers would extend the useful life of composite materials reinforced with plant fibers. The mass loss and enthalpy changes were investigated using the Perkin Elmer STA 6000 Model at STIC, Cochin, from the manufacturer Perkin Elmer Inc, Mumbai, India. The analysis is noted between 40 to 800 • C, with a heating rate of 20 • C for 60 s. Kinetic activation energy was evaluated from the DTG data using Coats-Redfern approximation. Differential scanning calorimetric values are obtained from the same instrument.

Thermal Conductivity Studies
Thermal responsiveness is a key factor in assessing the insulating utilities. With the use of Lee's disc arrangement, the K value of biofibers is calculated. After the temperature has stabilized, the disc setup is left to cool to mark the subsequent temperature decline. K value was determined using the following equation [36] where m-Lee's disc's mass, d-specimen thickness, x-specific heat, r, h-radius and Lee's disc's thickness, dT/dt-slope of temperature rate, T1-steady temperature and T2-temperature of Lee's disc.

Morphological Studies Using SEM
SEM examinations are used to inspect the flaws and smoothness on the fiber morphology. JEOL 6390LA/OXFORD XMXN, from JEOL India PVT LTD; South Delhi, a subsidiary company of JEOL Limited, Japan. It used to scan the surface configuration of fibers, with an accelerating voltage ranging from 0.5 to 30 kV.

FTIR Analysis
Vibrational assignments linked to the biofiber for the variable functional groups are emphasized using Fourier-transform infrared spectroscopy. With the instrumental support of FTIR-8400S spectrum from the manufacturer Shimadzu in Japan, using KBr matrix and a speed of 45 per minute, vibrational variations amongst the cellulosic groups of BP fibers are registered.

Chemical Composition
The cellular components cellulose, hemicellulose, and lignin are mostly resonated with the age of plants, the source of the fiber section, and the extraction pattern [37]. Standard analytical methods were used to determine the chemical composition of each fiber sample. The acid detergent method was used to measure cellulose content, while hemicellulose content was determined using the neutral detergent method. The Klason method was used to determine lignin content, and moisture content was measured by drying the samples at 105 • C until a constant weight was obtained. Soxhlet extraction with hexane as the solvent was used to determine the wax content. X-ray diffraction analysis was employed to determine the crystalline properties, including the crystallinity index and crystallite size. In addition, a Fourier-transform infrared (FTIR) spectroscopic study was also conducted to examine lignocellulosic fibers and determine their magnitudes of cellulosic composition. FTIR analysis is particularly useful in identifying the polymorphic structure of cellulose and in establishing the relationship between the OH bands and various components of biofibers such as cellulose, hemicellulose, pectin, and lignin, among others [38].
After being treated with KMnO 4 , the BP fiber's cellulose weight increased from 58.5% of raw fiber to 59.4%. Hemicellulose declined to 21.8% after KMnO 4 action, while the raw fiber possessed 40.13%. Lignin forms a connection between cellulose and hemicellulose polysaccharides. The fire-resistant behavior of lignin is a crucial quality to enforce for composites. Lignin was reduced by 13.5% after permanganate treatment, and the amount of wax weakened from 0.31% to 0.23% [32]. Table 2. compares the chemical analysis of different fibers [39,40]. The Chemical Tests Laboratory, SITRA, and Coimbatore provided the chemical analysis testing.

XRD Analysis
Upsurge in the crystalline unit was observed in the permanganate-treated fibers. Crystalline peak appeared at 23 • , and a diffracted amorphous was spotted around 18 • . Crystallinity index (CI) was computed to be 83.4%, with a crystallite size of 6.4 nm. CI for BP fibers is greater than Furcraea foetida (52.6%), Napier grass fibers (62.4%), Nelumbo nucifera (48%), Sansevieria ehrenbergii (52.27%), and Acacia planifrons (65.38%) [28,33]. The literature data show that higher variation in crystallinity index was registered for outer fibers than the inner core fibers of bamboo plant while subjected to alkali action. A good packing of cellulosic chains on a specific portion is responsible for this better crystalline output [41]. Surface morphology pictures of KMnO 4 -treated BP revealed more ordered packing of fibrils than raw BP.
Crystallite size of permanganate-treated fiber (6.4 nm) is bigger than flax (2.8 nm), Thespesia populnea (3.57 nm), and cotton (5.5 nm). The thermal characteristics are presumed to be improved by higher celluloses, larger CI, and CS because the intramolecular H-bond prevents thermal expansion, thereby imparting more stability to the fiber [42]. Smaller reaction sites reduce the surface area of crystallite, which increases the crystallite strength and durability, but conversely reduces the water absorption speed [43]. The merged XRD graph of raw and permanganate-treated BP is displayed in Figure 2, and the details on crystallinity are tabulated in Table 2.

Tensile Testing
Mechanical behavior of fibers is directly concerned with cellulose, as it gives sudden response to polymerization activities [44,45]. Tensile values of KMnO4-treated BP (198 MPa), followed by steam action for 15 min, was greater than raw BP fibers (92 MPa). Tensile modulus of treated BP is 4.40 GPa. Maximized values of fiber strength owes to the breakdown of amorphous entities housed within the fibrillar arrangement. Along with the exclusion of hemicellulose, lignin, wax, etc., from BP fiber, permanganate treatment rearranged the cellulosic chains by breaking and loosening the hydrogen network chain of the microfibrils [46]. Tensile values of treated BP are more than Manicaria saccifera (72.09 MPa), Coir fibers (95-174 MPa), and ariel roots of Banyan fiber and lower than Cissus quadrangularis (200.39 MPa) [47] and Artichoke fibers (201 MPa) [46,48,49]. Additionally, twisted single bundle fibers such as those from Nelumbo nucifera have higher tensile strength (427.7 MPa) than single fibers [43,44]. Tensile values of BP fiber are compared in Table 3 below.

Tensile Testing
Mechanical behavior of fibers is directly concerned with cellulose, as it gives sudden response to polymerization activities [44,45]. Tensile values of KMnO 4 -treated BP (198 MPa), followed by steam action for 15 min, was greater than raw BP fibers (92 MPa). Tensile modulus of treated BP is 4.40 GPa. Maximized values of fiber strength owes to the breakdown of amorphous entities housed within the fibrillar arrangement. Along with the exclusion of hemicellulose, lignin, wax, etc., from BP fiber, permanganate treatment rearranged the cellulosic chains by breaking and loosening the hydrogen network chain of the microfibrils [46]. Tensile values of treated BP are more than Manicaria saccifera (72.09 MPa), Coir fibers (95-174 MPa), and ariel roots of Banyan fiber and lower than Cissus quadrangularis (200.39 MPa) [47] and Artichoke fibers (201 MPa) [46,48,49]. Additionally, twisted single bundle fibers such as those from Nelumbo nucifera have higher tensile strength (427.7 MPa) than single fibers [43,44]. Tensile values of BP fiber are compared in Table 3 below.  [40] Structural applications are adhered by the cellulose availability and microfibrillar arrangement. Cellulosic microfibrils in the fiber axis lead to elongation and creation of microfibrillar angle, which is straight-away connected to the tensile strength [51]. Ductility of plant fibers show an inverse relation with microfibrillar angle. The bigger the orientation angle with fiber axis is, the higher the probability of fibers to upset with wrecking [52]. After being treated with permanganate, microfibrillar angle (MFA) of Butea fiber was shrunk from (21.11 ± 14.08 • ) to (16.88 ± 9.87 • ), which is comparable to other fibers such as Heteropogon contortus (14.53 ± 0.53 • ) [47] and Thespesia populnea (13.94 ± 1.21 • ) [47].

Tg-Dta Analysis
Fiber responses to various temperatures are studied using thermogram data. Tg-DTG curve is plotted in Figure 3a. Three-step degradation was seen in the permanganate-treated BP. Initial mass loss of 16% was noted between 50-200 • C, which is mainly due to the elimination of water. A profuse mass loss of 44% was recorded in the second stage of degradation up to 400 • C. Between 320-400 • C, cellulose exclusion has taken place, before which hemicellulose had expired between 200-320 • C. A final mass loss was stretched to 560 • C, focusing on the decomposition of lignin [18].

Tg-Dta Analysis
Fiber responses to various temperatures are studied using thermogram data. Tg-DTG curve is plotted in Figure 3a. Three-step degradation was seen in the permanganatetreated BP. Initial mass loss of 16% was noted between 50-200 °C, which is mainly due to the elimination of water. A profuse mass loss of 44% was recorded in the second stage of degradation up to 400 °C. Between 320-400 °C, cellulose exclusion has taken place, before which hemicellulose had expired between 200-320 °C. A final mass loss was stretched to 560 °C, focusing on the decomposition of lignin [18].
DTG curve revealed a significant disintegration peak at 336 °C, registering the removal of cellulose, closely matching the TG curve. The degradation peak for the raw BP was extended to 366 °C, higher than the KMnO4-treated fibers. Loss of lignin happens around 280-500 °C. Considerable loss of lignin nurtures thermal viability. However, chemical modification wiped out most lignin from the fiber arrangement leading to the earlier arrival of degradation temperature in the KMnO4-treated fiber than the raw BP. A comparison analysis showed that, among the fire retardant, rot retardant, water retardant, and raw jute fibers, raw fibers had the highest decomposition temperature [53]. In addition, incremented heat transfer to fibers would minimalize the melting heat, and it was noted to be lower in treated textile fiber than the untreated fiber [54]. These facts could have ignited the early decomposition in the permanganate-treated BP. The oxidation of hydrogen bonds between cellulose and hemicellulose caused by KMnO4 treatment has led to the formation of cellulose manganate complex [18]. This might have stretched the thermal stand by a temperature up to 240 °C. Similar degradation peaks were noticed in jute (365 °C), sisal (347 °C) and buriti (334 °C) [41].  Figure 4. A wide range of components move out from BP at varying temperatures. Moisture is the chief entity that gets removed within the first level of heating, all over 100 °C. In the KMnO4 treated BP, heat absorption left a peak around 400 °C, indicating the exemption of cellulose. Lignin takes a wider degradation rate as it is composed of numerous O2 functional group structures with diverse heat stability [55]. An exothermic peak at 459 °C liberated the lignified compartment from the treated BP. However, raw BP showcased an extended exclusion of lignin around 501 °C. Thermal behavior of BP fibers is listed in Table  4. DTG curve revealed a significant disintegration peak at 336 • C, registering the removal of cellulose, closely matching the TG curve. The degradation peak for the raw BP was extended to 366 • C, higher than the KMnO 4 -treated fibers. Loss of lignin happens around 280-500 • C. Considerable loss of lignin nurtures thermal viability. However, chemical modification wiped out most lignin from the fiber arrangement leading to the earlier arrival of degradation temperature in the KMnO 4 -treated fiber than the raw BP. A comparison analysis showed that, among the fire retardant, rot retardant, water retardant, and raw jute fibers, raw fibers had the highest decomposition temperature [53]. In addition, incremented heat transfer to fibers would minimalize the melting heat, and it was noted to be lower in treated textile fiber than the untreated fiber [54]. These facts could have ignited the early decomposition in the permanganate-treated BP. The oxidation of hydrogen bonds between cellulose and hemicellulose caused by KMnO 4 treatment has led to the formation of cellulose manganate complex [18]. This might have stretched the thermal stand by a temperature up to 240 • C. Similar degradation peaks were noticed in jute (365 • C), sisal (347 • C) and buriti (334 • C) [41].

Differential Scanning Calorimetric Data
DSC profiles of untreated and KMnO 4 -treated BP fibers are portrayed in Figure 4. A wide range of components move out from BP at varying temperatures. Moisture is the chief entity that gets removed within the first level of heating, all over 100 • C. In the KMnO 4 treated BP, heat absorption left a peak around 400 • C, indicating the exemption of cellulose. Lignin takes a wider degradation rate as it is composed of numerous O 2 functional group structures with diverse heat stability [55]. An exothermic peak at 459 • C liberated the lignified compartment from the treated BP. However, raw BP showcased an extended exclusion of lignin around 501 • C. Thermal behavior of BP fibers is listed in Table 4.

Activation Energy of BP
The activation energy of BP fibers was computed from Coasts-Redfern approximation [33].
A linear plot between log [−log(1 − α)/T 2 ] and 1000/T estimated the activation energy Ea, which is the prime factor in fixing the thermal stability of reinforcement. Kinetic activation energy for the permanganate-treated fibers are 62.80−63.46 KJ/mol, which is lower than the untreated BP 73.15 KJ/mol. Thermal stability of biofibers are projected through their degradation temperatures. Higher bond energy results in improved thermal stability and activation energy [56]. Thermal stability is dominant in the raw BP, and so Ea of permanganate-treated BP is lower than the raw BP. Ea curve is plotted in Figure 5.

. Activation Energy of BP
The activation energy of BP fibers was computed from Coasts-Redfern approximation [33].
A linear plot between log [−log(1 − α)/T 2 ] and 1000/T estimated the activation energy Ea, which is the prime factor in fixing the thermal stability of reinforcement. Kinetic activation energy for the permanganate-treated fibers are 62.80−63.46 KJ/mol, which is lower than the untreated BP 73.15 KJ/mol. Thermal stability of biofibers are projected through their degradation temperatures. Higher bond energy results in improved thermal stability and activation energy [56]. Thermal stability is dominant in the raw BP, and so Ea of permanganate-treated BP is lower than the raw BP. Ea curve is plotted in Figure 5.

Thermal Conductivity
Fibers show differences in thermal conduction in varying surroundings. Although straw fiber imbibed with clay matrix improves insulation, the composites' poor tensile strength limited its direct use in building applications [59], which neatly orients the role of conduction with the mechanical behavior. Lee's disc setup was employed to study the insulation behavior of Butea fibers. Fiber thickness and porosity alter the conductivity. K values for raw and KMnO4-treated fibers are 0.029 W/mk and 0.032 W/mk, respectively. Lower thermal stability than the raw BP could explain the treated BP's higher K value [56]. Permanganate-treated fibers gave higher Ea, which is compared with Areca husk fibers (0.021 W/mk) [60]. Cotton stalk fiber boards with heat conduction between 0.0585 and 0.0815 W/m K were created for ceiling applications [61]. Lowered K values provide a scope for utilizing Butea fibers for insulation applications when introduced in composites. Table  4. and Figure 6. give the linear action of thermal conductivity of raw and KMnO4-treated BP fiber.

Thermal Conductivity
Fibers show differences in thermal conduction in varying surroundings. Although straw fiber imbibed with clay matrix improves insulation, the composites' poor tensile strength limited its direct use in building applications [59], which neatly orients the role of conduction with the mechanical behavior. Lee's disc setup was employed to study the insulation behavior of Butea fibers. Fiber thickness and porosity alter the conductivity. K values for raw and KMnO 4 -treated fibers are 0.029 W/mk and 0.032 W/mk, respectively. Lower thermal stability than the raw BP could explain the treated BP's higher K value [56]. Permanganate-treated fibers gave higher Ea, which is compared with Areca husk fibers (0.021 W/mk) [60]. Cotton stalk fiber boards with heat conduction between 0.0585 and 0.0815 W/m K were created for ceiling applications [61]. Lowered K values provide a scope for utilizing Butea fibers for insulation applications when introduced in composites. Table 4. and Figure 6. give the linear action of thermal conductivity of raw and KMnO 4 -treated BP fiber.

Morphological Studies Using SEM
Surface morphologies are diligent while considering fibers to be paired with matrix. Figure 7a-f. show the surface variations in raw and treated fibers, respectively. Raw fibers

Morphological Studies Using SEM
Surface morphologies are diligent while considering fibers to be paired with matrix. Figure 7a-f. show the surface variations in raw and treated fibers, respectively. Raw fibers show projections on their surface, and fibrils are seen to be clouded with impurities, wax, hemicelluloses, and lignin. Microfibrils are unevenly oriented along the long axis. The presence of cellulose imparts a rough texture [62]. Figure 7b shows a flared structure in the raw BP, which could be easily distinguished from the ordered arrangements of treated BP. KMnO 4 action on the fibers might have eroded the amorphous constituents by breaking the linkage between the cellulose and hemicelluloses [63]. However, micrographs of permanganate-treated BP display a shallow depression along the long axis [64,65]. Fine pores appearing on the surface could indicate a good bonding between the reinforcement and matrix for composite-making [6]. The longitudinal arrangement of cellulosic components in Figure 7d of treated BP was more aligned than the raw BP in Figure 7a. Surface sections of KMnO 4 -treated BP was nearly rod-shaped, which resulted in the dismissal of linking agents within the BP's fiber space [42].

Morphological Studies Using SEM
Surface morphologies are diligent while considering fibers to be paired with matrix. Figure 7a-f. show the surface variations in raw and treated fibers, respectively. Raw fibers show projections on their surface, and fibrils are seen to be clouded with impurities, wax, hemicelluloses, and lignin. Microfibrils are unevenly oriented along the long axis. The presence of cellulose imparts a rough texture [62]. Figure 7b shows a flared structure in the raw BP, which could be easily distinguished from the ordered arrangements of treated BP. KMnO4 action on the fibers might have eroded the amorphous constituents by breaking the linkage between the cellulose and hemicelluloses [63]. However, micrographs of permanganate-treated BP display a shallow depression along the long axis [64,65]. Fine pores appearing on the surface could indicate a good bonding between the reinforcement and matrix for composite-making [6]. The longitudinal arrangement of cellulosic components in Figure 7d of treated BP was more aligned than the raw BP in Figure 7a. Surface sections of KMnO4-treated BP was nearly rod-shaped, which resulted in the dismissal of linking agents within the BP's fiber space [42].  Figure 8 spots the Fourier-transform infrared spectroscopic images of Butea parviflora. Vibrations due to amorphous groups are comparatively disappeared in the treated fiber. Wide and strong peaks witnessed within the limits 3450−3350 cm −1 are due to the disturbances executed by the hydrogen bonded OH group of the fiber [66][67][68] Absence of minor peaks witnessed in 1384 cm −1 might be due to the oxidation of lignin as a consequence of permanganate action [18].

FTIR Analysis
A peak rise in the area 646.78 cm −1 is involved in CS stretching [28]. Specific minor variations in peaks are observed for permanganate-treated BP, since several functional groups of amorphous constituents had removed during KMnO 4 action. Vibrations differing for untreated and permanganate-treated BP are spotted in Table 5 [69][70][71][72]. Figure 8 spots the Fourier-transform infrared spectroscopic images of Butea parviflora. Vibrations due to amorphous groups are comparatively disappeared in the treated fiber. Wide and strong peaks witnessed within the limits 3450−3350 cm −1 are due to the disturbances executed by the hydrogen bonded OH group of the fiber [66][67][68] Absence of minor peaks witnessed in 1384 cm −1 might be due to the oxidation of lignin as a consequence of permanganate action [18]. A peak rise in the area 646.78 cm −1 is involved in CS stretching [28]. Specific minor variations in peaks are observed for permanganate-treated BP, since several functional groups of amorphous constituents had removed during KMnO4 action. Vibrations differing for untreated and permanganate-treated BP are spotted in Table 5 [69][70][71][72].

Conclusions
Potassium permanganate-treated Butea parviflora (BP) fiber meets essential requirements for reinforcements. BP fibers have better physical and chemical behavior compared to most other bio fibers in the literature. BP fibers have low density (1.40 g/cc), making them suitable for lightweight composite applications.
Chemical analysis of permanganated BP showed a higher cellulose percentage (59.4%) and lowered hemicellulose content (21.8%). Semicrystalline fibers treated with permanganate showed an increase in the cellulosic CI and CS of 83.47% and 6.4 nm, respectively, resulting in better crystalline outcome, an essential behavior for bio-composites.
Tensile strength of fibers treated with KMnO 4 increased to 198 MPa from 92 MPa (raw BP), and a tensile modulus of 4.40 GPa was observed for treated BP. Microfibrillar angle in treated BP was reduced (16.88 ± 9.87 • ) compared to raw fiber (21.11 ± 14.08 • ), indicating improved strength performance of BP composites. DTG curve for KMnO 4 -treated and untreated fibers, respectively, showed a maximum degradation peak at 336 • C and 366 • C. Raw BP's thermal behavior was slightly superior to that of the treated BP.
Treating fibers with 0.1 M permanganate did not significantly increase the degradation temperature. Activation energy for the treated fiber was between 62.80-63.46 KJ/mol, comparatively lower than raw BP, indicating improved stability.
Thermal conductivity (K) was approximately 0.032 W/mk, which could be altered for insulation applications. SEM photographs revealed a challenging variation on the fiber surface, indicating excellent adhesion with the matrix. Spectroscopic vibrations of IR studies marked a minor variation in the various functional groups of cellular components.
Comprehensive analysis of all the above activities of BP fiber reveals a good standard for introducing this permanganate-treated Butea parviflora for making eco-friendly composites. This study highlights the potential of utilizing BP fiber in composite materials due to its low density, improved tensile strength, and remarkable crystalline behavior. Further research is planned to explore the benefits of surface modifications of Butea fibers and to develop BP fiber composites that maximize its properties.
In conclusion, the results of the study demonstrate that potassium permanganatetreated Butea parviflora fiber has the potential to serve as a suitable reinforcement material for biodegradable composites. The physical and chemical properties of the fiber, including its low density, high cellulose percentage, and improved crystalline outcome, make it a promising candidate for lightweight and strong biocomposites. The SEM photographs also indicate that the fiber surface has desirable variations for excellent adhesion with the matrix, further enhancing its potential as a reinforcement material. Moreover, the biodegradability of the BP fiber makes it an environmentally friendly option for developing sustainable and eco-friendly composites. Overall, this study highlights the potential of permanganatetreated BP fiber for developing biodegradable composites that have promising mechanical and thermal properties.